✦ LIBER ✦
The tetrahydropyranyl ether of (E)-3-bromo-3-trimethylsilyl-2-propen-1-ol, a single synthon for the (E)-β-formylvinyl anion and cation
✍ Scribed by R.Bryan Miller; Mohammed I. Al-Hassan
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 224 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The tetrahydropyranyl ether of (E)-3-bromo-3-trimethylsilyl-2-propen-l-01 can serve as a single synthon for both the (E)-B-formylvinyl anion and cation depending upon the manner in which the bromine group is stereospecifically replaced by an alkyl group.
mmol, 80% yield) of colorless product. GLC analysis revealed the product to be >99% the (E)-