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A Convenient Synthesis of 2,3-Diphenyl-2-cyanooxiranes

โœ Scribed by Takahashi, Kazumasa; Nishizuka, Toshio; Iida, Hirotada


Book ID
121378836
Publisher
Taylor and Francis Group
Year
1981
Tongue
English
Weight
201 KB
Volume
11
Category
Article
ISSN
0039-7911

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Treatment of 2-bromodeoxybenzoin with cyanide ion in the presence of adsorbent (silica gel or alumina) stereoselectively gives cis-2,3diphenyl-2-cyanooxirane in a good yield. The mechanism is discussed.

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