A convenient preparation of nitriles by reaction of free sulfimide with aldehydes
β Scribed by Naomichi Furukawa; Mitsuo Fukumura; Takeshi Akasaka; Toshiaki Yoshimura; Shigeru Oae
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- French
- Weight
- 111 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The reactfons of trimethylsilyl azide ITMSA) with various afdehydes were found to be versatile procedures for the synthesis of gem-and 1,3-dfazides, tetrazoles, and nitriles, whoae formation ~88 varied by controlling the quantities of TNSA, catalyst, and the reaction conditions.
Several diaryl(fluoro)-l 6 -sulfanenitriles 3 were synthesized by the reaction of S,S-diarylsulfimides 1 with Selectfluorβ’. This reaction also allows the first preparation of heterocyclic fluoro-l 6 -sulfanenitrile, 5-fluoro-10,10-dioxo-5,10-dihydro-5l 6 ,10l 6thianthren-5-nitrile (5) and its molecu