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A new method for the preparation of fluoro-λ6-sulfanenitriles: reaction of sulfimides with Selectfluor™

✍ Scribed by Takayoshi Fujii; Shinsuke Asai; Tomoyuki Okada; Wei Hao; Hiroyuki Morita; Toshiaki Yoshimura

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
113 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

Several diaryl(fluoro)-l 6 -sulfanenitriles 3 were synthesized by the reaction of S,S-diarylsulfimides 1 with Selectfluor™. This reaction also allows the first preparation of heterocyclic fluoro-l 6 -sulfanenitrile, 5-fluoro-10,10-dioxo-5,10-dihydro-5l 6 ,10l 6thianthren-5-nitrile (5) and its molecular structure was determined by X-ray crystallographic analysis.

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