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A convenient oxidation of hydroxylamines to nitroso-compounds

โœ Scribed by Taylor, Edward C.; Yoneda, Fumio


Book ID
111897440
Publisher
Royal Society of Chemistry
Year
1967
Weight
96 KB
Volume
4
Category
Article
ISSN
0009-241X

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A convenient synthesis of secondary hydr
โœ Ian A O'Neil; Ed Cleator; David J Tapolczay ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 95 KB

The oxidation of a range of b-cyanoethyl tertiary amines with mCPBA gives the corresponding N-oxides, which can be isolated or undergo Cope-elimination to give secondary hydroxylamines in excellent yield.