Generation of Acyl Nitroso Compounds by the Oxidation of N-Acyl Hydroxylamines with the Dessmartin Periodinane
β Scribed by Jenkins, Neil E.; Ware, Roy W.; Atkinson, Robert N.; King, S. Bruce
- Book ID
- 115461805
- Publisher
- Taylor and Francis Group
- Year
- 2000
- Tongue
- English
- Weight
- 211 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0039-7911
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π SIMILAR VOLUMES
Oxidation of hydroxamic acids in the presence of amines generates nitrous oxide (N20) and the corresponding amide. The identification of N:O suggests the intermediacy of nitroxyl (HNO). Retro-Diels Alder dissociation of cyclopentadiene-acyl nitroso compound cycloadducts releases N:O with amideformat
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