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Reactions of acyl nitroso compounds with amines: Production of nitroxyl (HNO) with the preparation of amides

✍ Scribed by Robert N Atkinson; Bernadette M Storey; S.Bruce King

Book ID
104258724
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
196 KB
Volume
37
Category
Article
ISSN
0040-4039

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✦ Synopsis

Oxidation of hydroxamic acids in the presence of amines generates nitrous oxide (N20) and the corresponding amide. The identification of N:O suggests the intermediacy of nitroxyl (HNO). Retro-Diels Alder dissociation of cyclopentadiene-acyl nitroso compound cycloadducts releases N:O with amideformation.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Reactions of Acyl N
ChemInform Abstract: Reactions of Acyl Nitroso Compounds with Amines: Production of Nitroxyl (HNO) with the Preparation of Amides.
✍ R. N. ATKINSON; B. M. STOREY; S. B. KING πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 2 views

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