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A CONVENIENT METHOD FOR THE PREPARATION OF α-KETOACETALS

✍ Scribed by Adamczyk, Maciej; Johnson, Donald D.; Mattingly, Phillip G.; Pan, You; Reddy, Rajarathnam E.

Book ID
118732973
Publisher
Taylor and Francis Group
Year
2002
Tongue
English
Weight
171 KB
Volume
32
Category
Article
ISSN
0039-7911

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The first synthesis of diazoesters by direct diazotization of amino acid esters was reported by Curtius I,\*) around 1900. Although this method is well suited for the preparation of diazoacetic ester, 3) it is generally inapplicable to the syntheses of a-substituted-a-diazoesters (I),\*) because of