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A convenient and general synthesis of 5-vinylhexofuranosides from 6-halo-6-deoxypyranosides

✍ Scribed by Masami Nakane; C.Richard Hutchinson; Harold Gollman

Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
265 KB
Volume
21
Category
Article
ISSN
0040-4039

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✦ Synopsis

The synthesis of five different 5,6-dideoxyhex-5-enofuranosides (5, 7, 9 and 11) proceeds in 30-60X overall yield in two steps from consnercially available 1-01-mefhyT pyrafi"osides by reductive B-elimination of the intermediate 6-bromo-6-deoxypyranosiaes.

We desired a test of the idea that reductive 5-elimination of CH30X from a l-Q-methyl-

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