The synthesis of five different 5,6-dideoxyhex-5-enofuranosides (5, 7, 9 and 11) proceeds in 30-60X overall yield in two steps from consnercially available 1-01-mefhyT pyrafi"osides by reductive B-elimination of the intermediate 6-bromo-6-deoxypyranosiaes. We desired a test of the idea that reducti
A general and convenient method for synthesis of 6-fluoro-6-deoxyhexoes
β Scribed by M. Sharma; W. Korytnyk
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 164 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Ring-fluorinated b-hydroxy a-amino methyl esters 3b,c were synthesized enantioselectively using Sharpless asymmetric aminohydroxylation. These were converted to 2-fluoro-and 6-fluoro-(2S,3R)-threo-(3,4-dihydroxyphenyl)serine 1b,c using our previously published procedure.
## Abstract A convenient method to synthesize radiolabelled glucoseβ1,6βbisphosphate (Glcβ1,6βP~2~) of high specific activity and in a high yield is reported. The method is based on enzymatic formation of glucoseβ6βP from glucose and ATP using hexokinase. The labelled glucoseβ6βP is then converted