Vernolic acid was prepared enantiospecifically from a readily available hydrate precursor and isomerized to (+)-coriolic acid using the methylmagnesium salt N-cyclohexylisopropylamine. Recently, (-)-vernolic acid' ( ) and (+)-coriolic acid2'3 (6) have attracted carboof
A concise synthesis of (R)-hydroxy-E,Z-diene fatty acids: preparation of 12(R)-hete, tetranor-12(R)-hete, and 13(R)-hode
โ Scribed by Sun Lumin; J.R. Falck; Michal L. Schwartzman
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 229 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Enantiocontrolled Synthesis of (11S,12S,13S)-(9Z,15Z)-and (11R,12S,13S)-(9Z,15Z)-11-Hydroxy-12,13-epoxy Octadecadienoic Acids by Means of the Sharpless Asymmetric Epoxidation of the Unsymmetrical Divinylcarbinol. -The enantioselective synthesis of the title compounds (V) and (VI), self-defensive su
Methyl 8-oxooctanoate-4,5-d and methyl 12-oxododecanoate-4,5,8,9-d4 were prepared for use as inzermediates in the synthesis of a series of labelled fatty acid methyl esters. Synthesis of the two compounds began with monoozonization and sodium acetate cleavage of 1,4-cyclooctadiene and 1,5,9-~yclodod