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A Concise Asymmetric Total Synthesis of (+)-Brevisamide

โœ Scribed by Herrmann, Aaron T.; Martinez, Steven R.; Zakarian, Armen

Book ID
115474322
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
682 KB
Volume
13
Category
Article
ISSN
1523-7060

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A formal total synthesis of (-)-brevisamide has been achieved. The synthetic approach highlights a chemoselective asymmetric dihydroxylation and a one-pot Fraser-Reid epoxidation/PMB protection reaction sequence.