A pulse radiolysis technique is known as a powerful method to study the primary processes in radiation chemistry. However, a large-sized accelerator and a huge cost should be required for the construction and operation of pulse radiolysis system. Very recently, the new compact picosecond pulse radio
A computerized pulse-radiolysis system
โ Scribed by Pieter W.F. Louwrier; Rob Buitenhuis; Erik Bracke; Kees Oostveen; Alexander H. Kruijer; Jaap Wisse; Louis Lindner
- Publisher
- Elsevier Science
- Year
- 1978
- Weight
- 371 KB
- Volume
- 151
- Category
- Article
- ISSN
- 0029-554X
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It was found that an absorption peak with 2m~ x = 560 nm in the pulse radiolysis of benzophenone-TBP system, which was assigned to the ketyl radical of benzophenone. The yields for the ketyl radical on benzophenone concentrations have been measured, which were well fitted with the Stern Volmer equat
A 5 hlcV proton accelerator hhs been used for pulse radiolysis of organic gases. The transient spectra obtained from the alkanes methane, ethane, propane. n.butanc and neopentane have tentatively been assigned to alkyl radicals. Some methodological aspects of this new technique are discussed.
Using the technique of pulse radiolysis, hydrated electrons have been produced and studied in quaternary microemulsion (sodium lauryl sulfate (NaLS)/water/cyclohexane/1-pentanol) system. Remarkably high lifetimes ( approximately 20 &mgrs) for hydrated electrons have been obtained. In general, these