β Scribed by Jin Haofang; Pan Xianming; Wu Jilan; Li Fengmei; Lui Andong; Gu Hongchun
No coin nor oath required. For personal study only.
It was found that an absorption peak with 2m~ x = 560 nm in the pulse radiolysis of benzophenone-TBP system, which was assigned to the ketyl radical of benzophenone. The yields for the ketyl radical on benzophenone concentrations have been measured, which were well fitted with the Stern Volmer equation. Analysis of the data, combining with the previous study, an energy transfer mechanism was proposed, the obtained GΒ°Bp, was 2.54 and the ratio of rate constants for TBP* dissociation to energy transfer was 840.
π SIMILAR VOLUMES
A pulse radiolysis technique is known as a powerful method to study the primary processes in radiation chemistry. However, a large-sized accelerator and a huge cost should be required for the construction and operation of pulse radiolysis system. Very recently, the new compact picosecond pulse radio
For pure tri-n-butyl phosphate (TBP) as well as solutions of cupric chloride in TBP and for mixtures of TBP with n-decane or solutions of cupric chloride therein, the density, viscosity, physical solubility of nitric oxide (NO) and its diffusion coefficient have been determined and a discussion is p