A comparative study of the use of triethylammonium salts of the [Fe2(CO)6(μ-CO)(μ-SR)]− anion in the synthesis of iron-gold clusters. Crystal structures of [Fe2(CO)6(μ-CO)(μ-SiPr)(μ-AuPPh3)] and [Fe2(CO)5(PPh3)(μ-SEt)2]
✍ Scribed by Esther Delgado; Elisa Hernández; Oriol Rossell; Miquel Seco; Enrique Gutiérrez Puebla; Caridad Ruiz
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 831 KB
- Volume
- 455
- Category
- Article
- ISSN
- 0022-328X
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The reaction of Na 2 [Fe(CO) 4 ] with Br 2 CF 2 in npentane generates a mixture of the compounds (CO) 3 Fe(l-CO) 3±n (l-CF 2 ) n Fe(CO) 3 (2, n = 2; 3, n = 1) in low yields with 3 as the main product. 3 is obtained free from 2 by reacting Br 2 CF 2 with Na 2 [Fe 2 (CO) 8 ]. The non-isolable monomeri
## By the reaction of [(p-RS) (p-CO)Fe, (CO),] [Et,NH] with MeAsI,, six new double cluster complexes, [(p-RS) (p-MeAs)Fe2(CO),12 (R = Et, Pr, 'Pr, Bu, C5Hll, Ph), were synthesized. The structure of the 'Pr analog was determined by single crystal X-ray diffraction techniques. Crystal data were as f