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Unexpected reactions of anionic intermediates [(μ-RS)(μ-Se)Fe2(CO)6]− with SO2Cl2. Synthesis of [(μ-RS)Fe2(CO)6]2(μ4-Se)(R = Ph, Et, nPr, tBu) and crystal structure of [(μ-PhS)Fe2(CO)6]2(μ4-Se)

✍ Scribed by Li-Cheng Song; Chao-Guo Yan; Qing-Mei Hu; Xiao-Ying Huang

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
199 KB
Volume
505
Category
Article
ISSN
0022-328X

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Synthesis and characterization of the double cluster complexes of [(μ-RS)(μ-MeAs)Fe2(CO)6]2—the crystal and molecular structure of [μ-iPrS)(μ-MeAs)Fe2(Co)6]2
✍ Li-Cheng Song; Qing-Mei Hu; Jun-Lin He; Ru-Ji Wang; Hong-Gen Wang 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 440 KB

## By the reaction of [(p-RS) (p-CO)Fe, (CO),] [Et,NH] with MeAsI,, six new double cluster complexes, [(p-RS) (p-MeAs)Fe2(CO),12 (R = Et, Pr, 'Pr, Bu, C5Hll, Ph), were synthesized. The structure of the 'Pr analog was determined by single crystal X-ray diffraction techniques. Crystal data were as f