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Synthesis and characterization of the double cluster complexes of [(μ-RS)(μ-MeAs)Fe2(CO)6]2—the crystal and molecular structure of [μ-iPrS)(μ-MeAs)Fe2(Co)6]2

✍ Scribed by Li-Cheng Song; Qing-Mei Hu; Jun-Lin He; Ru-Ji Wang; Hong-Gen Wang

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 440 KB
Volume: 3
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.520030503

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✦ Synopsis

By the reaction of [(p-RS) (p-CO)Fe, (CO),] [Et,NH]

with MeAsI,, six new double cluster complexes, [(p-RS) (p-MeAs)Fe2(CO),12 (R = Et, Pr, 'Pr, Bu, C5Hll, Ph), were synthesized. The structure of the 'Pr analog was determined by single crystal X-ray diffraction techniques. Crystal data were as follows: monoclinic,

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