A combined time-resolved and stereospeci
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Tineke A. Molenaar-Langeveld; Nico M. M. Nibbering
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Article
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1986
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John Wiley and Sons
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English
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It is shown by field ionization kinetics in combination with both site-specific and stereospecific D-labelling that the loss of a molecule of methanol from the molecular ion of methoxycyclohexane can occur via 1,4-and 1,3-eiiinations. The 1,4-elimination predominates at molecular ion lifetimes of rl