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A combined time-resolved and 2H/13 C labelling study of the elimination of hydrogen cyanide from the molecular ion of pyridine

✍ Scribed by E. Kluft; N.M.M. Nibbering


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
226 KB
Volume
69
Category
Article
ISSN
0168-1176

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It is shown by field ionization kinetics in combination with both site-specific and stereospecific D-labelling that the loss of a molecule of methanol from the molecular ion of methoxycyclohexane can occur via 1,4-and 1,3-eiiinations. The 1,4-elimination predominates at molecular ion lifetimes of rl