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An unusual pathway for the elimination of hydrogen cyanide from benzonitrile upon electron impact as revealed by 13C and 15N labelling

✍ Scribed by Tineke A. Molenaar-Langeveld; Roel H. Fokkens; Nico M. M. Nibbering


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
587 KB
Volume
21
Category
Article
ISSN
1076-5174

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Loss of hydrogen cyanide from monocyanop
✍ T. A. Molenaar-Langeveld; N. P. E. Vermeulen; N. M. M. Nibbering; R. P. Morgan; 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 732 KB

## Abstract Extensive ^13^C and ^15^N labelling has shown that the molecular ions of 2‐, 3‐ and 4‐cyanopyridine with lifetimes up to 10^−6^ s eliminate hydrogen cyanide originating predominantly from the ring (˜65%). Moreover, this hydrogen cyanide loss occurs after an equilibrated positional inter