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A time-resolved study of the methyl elimination from ionized homoadamantane in combination with2H- and13C-labelling

✍ Scribed by Els Kluft; Nico M.M. Nibbering; Helmut Schwarz; Roland Mu¨ller; Klaus-Peter Zeller


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
414 KB
Volume
73
Category
Article
ISSN
0168-1176

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✍ Tineke A. Molenaar-Langeveld; Nico M. M. Nibbering 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 791 KB

It is shown by field ionization kinetics in combination with both site-specific and stereospecific D-labelling that the loss of a molecule of methanol from the molecular ion of methoxycyclohexane can occur via 1,4-and 1,3-eiiinations. The 1,4-elimination predominates at molecular ion lifetimes of rl