The ready liberation of nitrous acid by 1,3bis (2-chloroethyl)-l-nitrosourea in hydrochloric acid solution has been utilized successfully in the development of a sensitive colorimetric method for its quantitative estimation in biological fluids. 1,3-Bis(2-chloroethyl)-l-nitrosourea (BCNU), a novel
A colorimetric method for the estimation of 2:2-bis-(p-chloro-phenyl)-1:1:1-trichloroethane (DDT)
✍ Scribed by Bradbury, F. R. ;Higgons, D. J. ;Stoneman, J. P.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1947
- Weight
- 472 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0368-4075
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
2:2‐Bis‐(p‐chlorophenyl)‐1:1:1‐trichlorocthanc reacts with hydroquinone and concentrated sulphuric acid at 100° to produce a wine‐red colour. The reaction has been studied and developed into a quantitative analytical method for the determination of DDT. The reaction is sufficiently specific to permit the determination of the purity of commercial samples of DDT with an accuracy of ± 1%.
📜 SIMILAR VOLUMES
## Abstract The 60 MHz ^1^H NMR spectra of __p__‐substituted phenyl 2‐chloro‐2‐fluoroethyl sulphides have shown characteristic patterns; in the ABC portion of an ABCX spin system (X = ^19^F) of the compounds, one of the subspectra shows an ABC pattern and the other apparently an AB~2~ pattern. Thes
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract To obtain information on the effects of nongenotoxic carcinogens at low doses for human cancer risk assessment, the carcinogenic potential of the organochlorine insecticide, 1,1‐bis(__p__‐chlorophenyl)‐2,2,2‐trichloroethane (DDT), in the liver was assessed in F344 rats. In experiment 1,
Whereas 3,4-bis(p-dimethylaminophenyl)-1,2-dithiete ( 18) is are suggested as key intermediates. X-ray crystallography of the disulfide 31 obtained from the main product 30 in equilibrium with its ring-opened valence isomer 19/19Ј, which can also exist as a solid, the analogously disubstituted unequ