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A collision complex model for the reaction CH2(1A1)+X→CH2(3B1)+X

✍ Scribed by Kenneth C. Kulander; John S. Dahler

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 468 KB
Volume: 41
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)85262-1

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Excess molar volumes at the temperature 298.15 K of the ternary mixtures: , and of the binary mixtures: , and {xCH3(CH2)5OH + (1-x)Cl(CH2)5CH3} were determined using a densimeter. All the experimental values were compared with the results obtained by empirical expressions for estimating ternary pr

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Excess molar volumes at the temperature 298.15 K were measured for , and {xCH3(CH2)4 CH3 +(1x)CH3(CH2)3OH}. Excess molar volumes were determined using an Anton Paar DMA 60/602 densimeter. The experimental values obtained in this work were compared with results obtained using methods which estimate

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Excess molar enthalpies at the temperature 298.15 K were measured for CH2)n-2CH3}, (n = 10, 12), using a Calvet microcalorimeter. The experimental results were compared with those calculated by using the Nitta-Chao, UNIFAC I, and UNIFAC II models.

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## Excess molar volumes at CH2 )n-2CH3}, (n= 10 or n = 12), and {xCH3(CH2)3CH2Cl + (1x)CH3(CH2)n-2CH3}, (n= 10 or n = 12), were determined using a densimeter Anton Paar DMA 60/602. All the experimental values were compared with the results obtained by empirical expressions for estimating ternar

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✍ M. López; E. Carballo; J.L. Legido; J. Salgado; J. Vijande; M.I. Paz Andrade 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 501 KB

Excess molar enthalpies at the temperature 298.15 K were measured for CH2)nCH3} (n = 9, 12), and {x2CH3(CH2)4CH3 + (1-x2)CH3(CH2)n-2CH3} (n=9, 12), using a Calvet microcalorimeter. The experimental results were compared with those calculated by using the Nitta-and-Chao model.