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A Class of Ruthenium(II) Catalyst for Asymmetric Transfer Hydrogenations of Ketones

✍ Scribed by Hayes, Aidan M.; Morris, David J.; Clarkson, Guy J.; Wills, Martin

Book ID
118212259
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
52 KB
Volume
127
Category
Article
ISSN
0002-7863

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## Abstract Tridentate __N,N,N__‐pyridinebisimidazolines have been studied as new ligands for the enantioselective transfer hydrogenation of prochiral ketones. High yields and excellent enantioselectivity up to >99 % __ee__ have been achieved with an __in situ__ generated catalytic system containin