A chiroptical method for determining the absolute configuration of allylic alcohols
β Scribed by Harada, Nobuyuki; Iwabuchi, Jun; Yokota, Yoichi; Uda, Hisashi; Nakanishi, Koji
- Book ID
- 121861762
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 254 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0002-7863
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After the conformation I was clarified to 5a,lOa-cis-solidagolactones by lH NMR measurement with Eu(dpm)3 and chemical transformations, the CD homoallylic benzoate chirality method was applied to the homoallylic alcohol system of solidagolactone IV (la) for a chiroptical determination of the absolut
## Abstract Hydroxyiridals β monocyclic triterpenoids β are found abundantly in sword lilies. They feature a homofarnesyl side chain that is hydroxylated at one of the allylic methylene groups, which gives rise to a chiral carbon atom. The absolute configuration of six hydroxyiridals from different