## Abstract Both (2__R__)‐ and (2__S__)‐hydroxy derivatives of (+)‐exo‐brevicomin {5‐methyl‐6,8‐dioxabicyclo[3.2.1]octan‐2‐ol; 1 and 2} were synthesized by employing Sharpless asymmetric dihydroxylation as the key reaction.
A chiron approach to (1R,2R,5S,7S)-2-hydroxy-exo-brevicomin: a component of the volatiles produced by the male mountain pine beetle, Dendroctonus ponderosae
✍ Scribed by D. Naveen Kumar; B. Venkateswara Rao; G.S. Ramanjaneyulu
- Book ID
- 108283935
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 120 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0957-4166
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Pheromone Synthesis. Part 183. Synthesis of (1R,2R,5S,7R)-and (1R,2S, 5S,7R)-2-Hydroxy-exo-brevicomin, the Components of the Male-Produced Volatiles of the Mountain Pine Beetle, Dendroctonus ponderosae. -Both title compounds (V) and (VI) are synthesized via asymmetric dihydroxylation as the key ste
## Abstract Both (1__R__)‐ and (1__S__)‐hydroxy derivatives of (+)‐exo‐brevicomin {(1__R__,1′__R__,5′__R__,7′__R__)‐1‐(5′‐methyl‐6′,8′‐dioxabicyclo[3.2.1]‐octyl)ethanol (1) and its (1__S__)‐isomer (2)} were synthesized by employing Sharpless asymmetric dihydroxylation as the key reaction.