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A Chemical Synthesis of 3-Deoxy-D- manno -2-octulosonic Acid from D-mannose

✍ Scribed by Ichiyanagi, Tsuyoshi; Sakamoto, Naoko; Ochi, Kazutoshi; Yamasaki, Ryohei

Book ID
121237570
Publisher
Taylor and Francis Group
Year
2009
Tongue
English
Weight
525 KB
Volume
28
Category
Article
ISSN
0732-8303

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KDO (1) is synthesized in five steps, starting from 1,2-to the carbonate 9. Silicon-induced lactonization affords the lactone 10, which can be converted into NH 4 -KDO by anhydro-3,4:5,6-di-O-isopropylidene-D-mannitol ( 6). The epoxide 6, obtained from D-mannitol (2), reacts with lithiated standard