## Abstract Two novel constituents of __Burley__ tobacco condensate were shown to be 5‐(4‐methyl‐2‐furyl)‐6‐methylheptan‐2‐one (__solanofuran__, **4**) and 3,4,7‐trimethyl‐1,6‐dioxa‐spiro[4.5]‐dec‐3‐en‐2‐one (__spiroxabovolide__, **6**). These structures were deduced from spectral data and confirme
A Chemical Study of Burley Tobacco Flavour (Nicotiana tabacumL.) V. Identification and Synthesis of the Novel Terpenoid Alkaloids 1, 3, 6, 6-Tetramethyl-5, 6, 7, 8-tetrahydro-isoquinolin-8-one and 3, 6, 6-Trimethyl-5,6-dihydro-7H-2-pyrindin-7-one
✍ Scribed by Edouard Demole; Cécile Demole
- Publisher
- John Wiley and Sons
- Year
- 1975
- Tongue
- German
- Weight
- 601 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
GLC. allowed the isolation of 1, 3, 6, 6‐tetramethyl‐5, 6, 7, 8‐tetrahydro‐isoquinolin‐8‐one (A) and 3,6,6‐trimethyl‐5,6‐dihydro‐7H‐2‐pyrindin‐7‐one (D) from Burley tobacco condensate (about 0.1% each). The structures and syntheses of these novel terpenoid alkaloids are described, and a possible way for their formation in tobacco is suggested.
📜 SIMILAR VOLUMES
## Abstract 5′‐Mercapto‐1′__H__‐1,2,4‐triazol‐3′‐yl‐isoquinolinium salts **(6)** were synthesised by the reaction of __ortho__‐acyl phenylacetones **(2)** or the corresponding pyrylium salts **(3)** and 5‐amino‐2,3‐dihydro‐1__H__‐1,2,4‐triazole‐3‐thione **(5)**. Treatment of thioles **6** withα,ω‐d