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A Biomimetically Inspired Synthesis of the Dehydropiperidine Domain of Thiostrepton

โœ Scribed by K. C. Nicolaou; Marta Nevalainen; Brian S. Safina; Mark Zak; Stephan Bulat

Book ID
101372845
Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
142 KB
Volume
41
Category
Article
ISSN
0044-8249

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Synthetic studies on the thiostrepton fa
Synthetic studies on the thiostrepton family of peptide antibiotics: synthesis of the tetrasubstituted dehydropiperidine and piperidine cores
โœ Syuhei Higashibayashi; Kimiko Hashimoto; Masaya Nakata ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 117 KB

The tetrasubstituted dehydropiperidine and piperidine cores of the thiostrepton family of peptide antibiotics were synthesized which featured the coupling between the azomethine ylide and the enantiopure sulfinimine, and the subsequent stereoselective reduction of the six-membered imine.