A biogenetic-type asymmetric synthesis of natural (+)-maritidine from L-tyrosine
β Scribed by Shun-ichi Yamada; Kiyoshi Tomioka; Kenji Koga
- Book ID
- 104212912
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 202 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
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## Abstract magnified image Using Lβtyrosine as a chiral starting material, we developed an efficient synthetic route to (β)βMY 336a. A key step in the sequence is a highly regioβ and diastereoselective intermolecular PictetβSpengler cyclization reaction between amino alcohol and benzyloxyacetalde
f)-Aplysiadiol (1). a brominated diterpene having a ram, prenylated eudesmane skeleton was synthesized starting with (\*)-hedycaryol(2) in a biogenetic manner. Aplysiadiol(1) isolated ftom the Japanese marine mollusc ApZysti kurodai is a brominated diterpene having a rate, prenylated eudesmane skel