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A 1,4-cycloaddition reaction of cyclooctatetraene

โœ Scribed by A.B. Evnin; R.D. Miller; G.R. Evanega


Book ID
104215286
Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
143 KB
Volume
9
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


We have found that reaction of cyclooctatetraene (I_) with 4-phenyl-1,2,4-triazoline-3,3-dione (2) at 23O affords 4-pbenyl-2,4,6-triaza[5.4.2.O2~6]trlcyclotrideca-8,lO,~-triene-3,5-dime (2). The result Is of considerable Interest since examples of 1,4-cycloadditlons


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## Abstract The reaction of 1,4โ€dihydroโ€1,4โ€epoxynaphthalene with cyclooctatetraene at 130ยฑ5ยฐ for 14 days gave the four products 2a,3,3a,4,9,9a,10,10aโ€octahydroโ€4,9โ€epoxyโ€3,10โ€ethenocyclobuta[__b__]anthracene (**13**), 25โ€oxanonacyclo[10.10.2.2^5,9^.1^14,21^.0^2,11^.0^3,10^.0^4,6^.0^13,22^.0^15,20^