A 1,4-cycloaddition reaction of cyclooctatetraene
โ Scribed by A.B. Evnin; R.D. Miller; G.R. Evanega
- Book ID
- 104215286
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 143 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
We have found that reaction of cyclooctatetraene (I_) with 4-phenyl-1,2,4-triazoline-3,3-dione (2) at 23O affords 4-pbenyl-2,4,6-triaza[5.4.2.O2~6]trlcyclotrideca-8,lO,~-triene-3,5-dime (2). The result Is of considerable Interest since examples of 1,4-cycloadditlons
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## Abstract The reaction of 1,4โdihydroโ1,4โepoxynaphthalene with cyclooctatetraene at 130ยฑ5ยฐ for 14 days gave the four products 2a,3,3a,4,9,9a,10,10aโoctahydroโ4,9โepoxyโ3,10โethenocyclobuta[__b__]anthracene (**13**), 25โoxanonacyclo[10.10.2.2^5,9^.1^14,21^.0^2,11^.0^3,10^.0^4,6^.0^13,22^.0^15,20^