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1,4-Cycloaddition of Tetracyanoethylene to Methoxy- and Phenoxy-cyclooctatetraene

โœ Scribed by Dr. Johann Gasteiger; Prof. Rolf Huisgen

Book ID
101544070
Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
216 KB
Volume
11
Category
Article
ISSN
0044-8249

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## Abstract The reaction of 1,4โ€dihydroโ€1,4โ€epoxynaphthalene with cyclooctatetraene at 130ยฑ5ยฐ for 14 days gave the four products 2a,3,3a,4,9,9a,10,10aโ€octahydroโ€4,9โ€epoxyโ€3,10โ€ethenocyclobuta[__b__]anthracene (**13**), 25โ€oxanonacyclo[10.10.2.2^5,9^.1^14,21^.0^2,11^.0^3,10^.0^4,6^.0^13,22^.0^15,20^