## Abstract Ferrocenyl nitrones derived from aldehydes or oximes react with electron deficient alkenes to give ferrocenylisoxazolidines. 5βMethoxycarbonylisoxazolidines are further transformed to ferrocenylβpyrrolidinones by reductive cleavage. The regioβ and stereoselectivity of the reactions are
β¦ LIBER β¦
Cycloaddition reactions of nitrones to cyclooctatetraene and its derivatives
β Scribed by G. Bianchi; A. Gamba; R. Gandolfi
- Book ID
- 103396034
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 553 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4020
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The intramolecular 1,3-dipolar cycloaddition of Ο-unmolecular cycloaddition, followed by reductive opening of the isoxazolidine ring, produced five-and seven-membered saturated chiral nitrones is described. Starting materials for this reaction are O-protected chiral cyanohydrins, prepared ring compo