96/03785 ESA study of C60 n-anion radicals in DMSO solution
- Publisher
- Elsevier Science
- Year
- 1996
- Weight
- 183 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0140-6701
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π SIMILAR VOLUMES
ESR spectra of CsO radical anions were detected for &/MCHX and C,,/MTHF solid solutions which were y-irradiated at 77 K and subsequently annealed at 1 IO-140 K. The g-factors were 2.00 19 and 1.9997 for C,,JMCHX (or CJMCHX-d14) and CJMTHF, respectively. AH,,=O.26 mT was obtained for those solutions
It is shown by near-IR that the anion radicals C70 and C2o are formed in vacuum by interaction between the fullerenes C70 and 1-amino-3-propanol (AP) and 1,5-diaminopentane (DAP). The temperature dependence of the ESR spectra for the systems C60-AP, CTo-AP and C7o-DAP were studied. At low temperatur
The time-of-flight (TOF) technique for mobility measurements in the condensed phase has been applied to solutions of CsO in n-hexane. The C6u radical anion has a mobility of 5.6x 10e4 cm'V\_' s-', and a Stokes radius of 5.0 A, which agrees remarkably well with the van der Waals radius of the Cso mol