Peri interactions in naphthalenes and anthracenes cause molecular distortions which may result in unusual reactions.' Anthracenes with a double-peri interaction (a, substituents at Cl, 8 and 9) or with two peri interactions (Le., substituents at Cl, 9 and either C4, 10 or C5, 10) may be unstable rel
✦ LIBER ✦
9,10-dewar-anthracene
✍ Scribed by Wolfgang Pritschins; Wolfram Grimme
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 212 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The title compound 8 has been synthesized and the kinetic parameters of its aromatization have been measured. In the key-step of the synthesis g,6-dihydrobenzocyclobutadiene is used, a new and powerful diene that cycloadds along its axis.
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