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9,9′-Bi-10H-anthracene-9,9′-diol

✍ Scribed by Liu, Jian-Cheng ;Jin, Shuo ;Liu, Bo ;Guo, Jian-Ping

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
235 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 28 H 22 O 2 , is a intermediate in the synthesis of 10,10 0 -dibromo-9,9 0 -bianthracenyl. The molecule forms both intra-and intermolecular O-HÁ Á ÁO hydrogen bonds.

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The title compound 8 has been synthesized and the kinetic parameters of its aromatization have been measured. In the key-step of the synthesis g,6-dihydrobenzocyclobutadiene is used, a new and powerful diene that cycloadds along its axis.