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Decamethylanthracene and its 9,10-‘DEWAR’ isomer

✍ Scribed by Harold Hart; Bernd Ruge

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
204 KB
Volume
18
Category
Article
ISSN
0040-4039

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✦ Synopsis

Peri interactions in naphthalenes and anthracenes cause molecular distortions which may result in unusual reactions.' Anthracenes with a double-peri interaction (a, substituents at Cl, 8 and 9) or with two peri interactions (Le., substituents at Cl, 9 and either C4, 10 or C5, 10) may be unstable relative to the tautomeric form in which the central ring is not aromatic.2 For example, 1,4,5,8,9_pentamethylanthracene, 394 which has a double-peri methyl interaction,

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