In the title compound, C~16~H~11~BrO, the bromoacetyl group makes an angle of 105.8 (1)° with the anthracene ring system. The crystal packing is consolidated by C—H...π, Br...π and C—H...O interactions.
9-(Methoxymethyl)anthracene
✍ Scribed by Liu, Jie ;Wei, Guo-Hua ;Ping, Guang-Ju ;Ma, Jian-Fang
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 633 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C~16~H~14~O, crystallizes with two independent molecules in the asymmetric unit, one of which lies on a crystallographic mirror plane. Intermolecular C—H...O hydrogen bonds link the molecules into infinite one-dimensional chains.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 291 K Mean '(C±C) = 0.002 A Ê R factor = 0.052 wR factor = 0.140 Data-to-parameter ratio = 12.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound 8 has been synthesized and the kinetic parameters of its aromatization have been measured. In the key-step of the synthesis g,6-dihydrobenzocyclobutadiene is used, a new and powerful diene that cycloadds along its axis.
The title compound, C 28 H 22 O 2 , is a intermediate in the synthesis of 10,10 0 -dibromo-9,9 0 -bianthracenyl. The molecule forms both intra-and intermolecular O-HÁ Á ÁO hydrogen bonds.