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9-(4-Ethynylphen­yl)-9H-carbazole

✍ Scribed by Lin, Hai-Yao ;Zhang, Xiao-Bo ;Lu, Ping

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
398 KB
Volume
61
Category
Article
ISSN
1600-5368

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9-(4-Fluoro­benz­yl)-9H-carbazole
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In the title compound, C~19~H~14~FN, the carbazole ring system is essentially planar and forms a dihedral angle with the benzene ring of 87.4 (4)°.

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In the title compound, C 18 H 12 N 2 O 2 , the carbazole ring system is essentially planar and makes a dihedral angle of 53.08 (4) with the plane of the nitrobenzene ring. In the crystal structure, inversion-related molecules form a C-HÁ Á ÁO hydrogen-bonded dimer.

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In the title compound, C 21 H 19 N, the carbazole ring system is essentially planar. The structure is stabilized by bothand C-HÁ Á Á interactions. The ethylbenzene ring was found to be disordered.

9-(4-Methyl­benz­yl)-9H-carbazole
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The title compound, C 20 H 17 N, was synthesized by N-alkylation of 1-chloromethyl-4-methylbenzene with carbazole. The carbazole ring system is essentially planar, with a mean deviation of 0.029 A ˚, and makes a dihedral angle of 109 ( 5) with the plane of the benzene ring.

9-(4-Chloro­benz­yl)-9H-carbazole
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✍ Cui, Jian-Lan ;Cao, Duan-Lin ;Guo, Wen-Long ;Huang, Peng-Mian 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 108 KB

The title compound, C 19 H 14 ClN, was synthesized by Nalkylation of carbazole with 1-chloro-4-(chloromethyl)benzene. The carbazole ring system is essentially planar and makes a dihedral angle of 109.6 (5) with the plane of the benzene ring.

9-[4-(4-Bromo­styr­yl)phen­yl]-9H-carbaz
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The title molecule, C~26~H~18~BrN, adopts the __Z__ configuration and shows normal values of bond lengths and angles. The crystal packing is stabilized by van der Waals forces.