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9-(4-Chlorobenzyl)-9H-carbazole

✍ Scribed by Cui, Jian-Lan ;Cao, Duan-Lin ;Guo, Wen-Long ;Huang, Peng-Mian

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 108 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536806000249

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✦ Synopsis

The title compound, C 19 H 14 ClN, was synthesized by Nalkylation of carbazole with 1-chloro-4-(chloromethyl)benzene. The carbazole ring system is essentially planar and makes a dihedral angle of 109.6 (5) with the plane of the benzene ring.

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The title compound, C 20 H 17 N, was synthesized by N-alkylation of 1-chloromethyl-4-methylbenzene with carbazole. The carbazole ring system is essentially planar, with a mean deviation of 0.029 A ˚, and makes a dihedral angle of 109 ( 5) with the plane of the benzene ring.

9-(2,6-Dichlorobenzyl)-9H-carbazole

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In the title compound, C 19 H 13 Cl 2 N, the dihedral angle between the dichlorobenzyl ring and the carbazole ring system is 92.6 (6) . In the crystal structure, molecules are linked via intermolecular ClÁ Á ÁCl interactions.

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9-(4-Chloro­benz­yl)-9H-carbazole

✦ Synopsis

9-(4-Chlorobenzyl)-9H-carbazole