In the title compound, C~19~H~14~FN, the carbazole ring system is essentially planar and forms a dihedral angle with the benzene ring of 87.4 (4)°.
9-(2,6-Dichlorobenzyl)-9H-carbazole
✍ Scribed by Shi, Ming-Wang ;Chen, Xi-Ling ;Lang, Jian-Feng ;Wang, Jian-Hua
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 234 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 19 H 13 Cl 2 N, the dihedral angle between the dichlorobenzyl ring and the carbazole ring system is 92.6 (6) . In the crystal structure, molecules are linked via intermolecular ClÁ Á ÁCl interactions.
📜 SIMILAR VOLUMES
In the title compound, C 21 H 19 N, the carbazole ring system is essentially planar. The structure is stabilized by bothand C-HÁ Á Á interactions. The ethylbenzene ring was found to be disordered.
The title compound, C 20 H 17 N, was synthesized by N-alkylation of 1-chloromethyl-4-methylbenzene with carbazole. The carbazole ring system is essentially planar, with a mean deviation of 0.029 A ˚, and makes a dihedral angle of 109 ( 5) with the plane of the benzene ring.
The title compound, C 19 H 14 ClN, was synthesized by Nalkylation of carbazole with 1-chloro-4-(chloromethyl)benzene. The carbazole ring system is essentially planar and makes a dihedral angle of 109.6 (5) with the plane of the benzene ring.
The title compound, C 14 H 11 Br 2 N, was synthesized by Nalkylation of bromoethane with 3,6-dibromo-9H-carbazole. The carbazole ring system is essentially planar and makes a dihedral angle of 94.7 (3) with the plane formed by the ethyl C and carbazole N atoms.