8,8′-Methylenebis(7,10-dihydroxy-1,3,6,6-tetramethyl-3,4-dihydro-1H-benzo[g]isochromen-9-one)
✍ Scribed by Fun, Hoong-Kun ;Boonnak, Nawong ;Chantrapromma, Suchada
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 231 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 23 H 24 O 8 , the central methylene unit that links the two sets of fused rings lies on a crystallographic twofold rotation axis. The isochromene skeleton is not planar, with the pyran ring in an envelope conformation. Intra-and intermolecular O-HÁ Á ÁO hydrogen bonds and weak C-HÁ Á ÁO and C-HÁ Á Á interactions stabilize the crystal structure.
📜 SIMILAR VOLUMES
The title compound, C 30 H 32 ClNO 3 , was synthesized by the reaction of dimedone with 4-methoxybenzaldehyde and 4chlorobenzenamine in water. The dihydropyridine ring is in a boat conformation. Both cyclohexene rings adopt envelope conformations. The chlorophenyl and methoxyphenyl rings form dihedr
The title compound, C 23 H 25 BrO 3 , was synthesized by the reaction of p-bromobenzaldehyde with dimedone and HClO 4 / SiO 2 in EtOH. In the molecule, the dihydropyran ring adopts a boat conformation and the two cyclohexene rings are in a trans conformation.
## Abstract 7‐Alkanoyloxy‐3,7‐dimefhyl‐7,8‐dihydro‐6__H__‐isochromene‐6,8‐diones **12‐15** were synthesized in 69‐16% yields from the reaction of 2,4‐dihydroxy‐3‐methyl‐6‐(2‐oxopropyl)benzaldehyde **11** with __p__‐toluenesulfonic acid in various carboxylic acids such as acetic acid, propionic acid