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10-(2-Fluorophenyl)-9-(4-methoxyphenyl)-3,3,6,6-tetramethyl-3,4,6,7-tetrahydroacridine-1,8(2H,5H,9H,10H)-dione

✍ Scribed by Büyükgüngör, Orhan ;Kaya, Muharrem ;Odabaşoğlu, Mustafa ;Yıldırır, Yılmaz


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
468 KB
Volume
63
Category
Article
ISSN
1600-5368

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10-(4-Chlorophenyl)-9-(4-methoxyphenyl)-
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The title compound, C 30 H 32 ClNO 3 , was synthesized by the reaction of dimedone with 4-methoxybenzaldehyde and 4chlorobenzenamine in water. The dihydropyridine ring is in a boat conformation. Both cyclohexene rings adopt envelope conformations. The chlorophenyl and methoxyphenyl rings form dihedr

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The title compound, C 23 H 25 BrO 3 , was synthesized by the reaction of p-bromobenzaldehyde with dimedone and HClO 4 / SiO 2 in EtOH. In the molecule, the dihydropyran ring adopts a boat conformation and the two cyclohexene rings are in a trans conformation.

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The asymmetric unit of the title compound, C 19 H 16 FN 5 O 4 , contains two independent molecules. The dihedral angles between the main planes and the fluorophenyl rings in the two molecules are 83.24 (5) and 71.76 (4) . Weakstacking interactions may be effective in the stabilization of the crystal