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9-(4-Bromophenyl)-3,3,6,6-tetramethyl-3,4,6,7-tetrahydro-2H-xanthene-1,8(5H,9H)-dione

✍ Scribed by Bigdeli, M. Ali ;Mahdavinia, Gholam Hossein ;Amani, Vahid


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
646 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, C 23 H 25 BrO 3 , was synthesized by the reaction of p-bromobenzaldehyde with dimedone and HClO 4 / SiO 2 in EtOH. In the molecule, the dihydropyran ring adopts a boat conformation and the two cyclohexene rings are in a trans conformation.


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10-(4-Chlorophenyl)-9-(4-methoxyphenyl)-
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The title compound, C 30 H 32 ClNO 3 , was synthesized by the reaction of dimedone with 4-methoxybenzaldehyde and 4chlorobenzenamine in water. The dihydropyridine ring is in a boat conformation. Both cyclohexene rings adopt envelope conformations. The chlorophenyl and methoxyphenyl rings form dihedr

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In the title compound, C 26 H 27 NO 4 , the central ring of the xanthene moiety is planar and the two outer rings are in halfboat conformations. The molecular packing in the crystal structure is stabilized by N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds in addition to van der Waals forces.