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8,8'-Bis[tetracyclo[5.1.0.01,6.02,7]octane], a coupled [1.1.1]propellane: synthesis and structure

✍ Scribed by Kottirsch, Georg.; Polborn, Kurt.; Szeimies, Guenter.


Book ID
127219743
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
448 KB
Volume
110
Category
Article
ISSN
0002-7863

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The synthesis of the hydrocarbons 4-5 has been achieved via Wittig reaction from the diketones J-2. By means of He(I)photoelect spectroscopy it is shown that the interaction between the r-fragments in 2-g increases strongly. Recently we demonstrated by means of He(I)photoelect (PE) spectroscopy