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Tetracyclo[5.2.0.01,6.02,7]nonane, A [2.1.1]propellane derivative as a reaction intermediate

✍ Scribed by Jan Morf; Günter Szeimies


Book ID
104219290
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
191 KB
Volume
27
Category
Article
ISSN
0040-4039

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Reactions of 1,3,5-Tri-tert-butylcyclope
✍ Dehmlow, Eckehard V. ;Bollmann, Christof 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 332 KB

Title compound 1 is sterically shielded to such an extent that many "normal" reactions cannot occur. It is possible, however, to prepare the carboxylic acid 2, its acyl chloride 3 and the oxidation product 4. Furthermore, halogen substitutions to yield 5 and 6 and trialkylstannations to give 8a, b c