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Reaction of 1-bromo-7-chloropentacyclo[5.2.0.02,6.03,9.05, 8]nonane with tert-bithyllithium: Evidence for 1(7)-homocubene

✍ Scribed by Jörg Schäfer; Günter Szeimies


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
97 KB
Volume
29
Category
Article
ISSN
0040-4039

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bidentate coordination of unsaturated complex fragments. To our knowledge the only other bridge-forming S4 ligands are found in copper([) polysulfide clusters, in which two copper centers are each bridged by a terminal member of the S, chain.r31 The formation of 1 proceeds via several intermediates