Five highly excited (1)Sigma(+)(g) states of Na(2) were observed for the first time by pulsed optical-optical double resonance (OODR) fluorescence excitation spectroscopy. Three of the five states are assigned to the 6svarsigma (1)Sigma(+)(g), 6dvarsigma (1)Sigma(+)(g), and 7dvarsigma (1)Sigma(+)(g)
8–10sς, 8–10dς 1Σ+g, and 10–15dπ 1Πg Rydberg States of Na2
✍ Scribed by X. Dai; J. Xiang; Y. Liu; Li Li
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 109 KB
- Volume
- 198
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
With a sensitive space-charge-limited diode ionization detector, we studied 8-10svarsigma, 8-10dvarsigma (1)Sigma(+)(g), and 10-15dpi (1)Pi(g) Rydberg states of Na(2) and obtained their molecular constants for the first time. It is the first successful example of a diode ionization detector that is used in a pulsed OODR molecular spectroscopy experiment. Copyright 1999 Academic Press.
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