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81. Equilibrium conditions and kinetics of the intercalation of AiCl3 and FeCl3 with graphite

✍ Scribed by Alfred R. Feichtinger; Alfons Baiker; Werner Richarz


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
255 KB
Volume
20
Category
Article
ISSN
0008-6223

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✦ Synopsis


The amount of expansion on exfoliation is determined principally by the parent stage rather than the actual intercalate concentration. The amount of expansion increases with increasing stage of the parent compound before desorption. For the same parent stage, a higher concentration produces a larger expansion.

Staging ln graphite compounds with XeOF,


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The formation process of the ternary AICI,-FeCI,-graphite intercalation compounds (GICs) was studied by using three different reaction paths at 150Β°C. In the reaction of stage I, FeCI,-GICs with AICI,, the exchange of intercalated FeCh for AICll occurred and, consequently, the formation of the "mixe

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