The formation process of the ternary AICI,-FeCI,-graphite intercalation compounds (GICs) was studied by using three different reaction paths at 150ยฐC. In the reaction of stage I, FeCI,-GICs with AICI,, the exchange of intercalated FeCh for AICll occurred and, consequently, the formation of the "mixe
Synthesis and local analysis of ternary FeCl3-PbCl2-graphite intercalation compounds
โ Scribed by Masahiko Ohira; Michio Inagaki; Noboru Nakagomi
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 628 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0008-6223
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Stage 2 and 3 FeCl,-graphite intercalation compounds (GICs) and stage l-3 ICI-GICs are prepared by a two-bulb method. The stage structures of the GICs are studied by X-ray diffraction, and ihe\_GICs are characterized by the full width at half maximum of the (001) diffraciion peaks. The effective Deb
Stage-n Fe&GICs (n = 2,3) prepared in the standard two-zone method were oxidized galvanostatically in H,SO,. The electrode potential vs. electric quantity curves observed during the treatment and the X-ray powder patterns of the products showed clearly the intercalation of H,SO, into FeCI,-GICs and
## We have investigated the surface structure of stage-l CuCI,-and FeCI,-graphite intercalation compounds (GICs) by atomic force microscopy. For both GICs, the atomically flat terrace-step structures have been easily obtained by cleaving and, on the terraces, interesting incommensurate superlatti