79. On the mechanism of intercalation of FeCl3 in graphite from solution

81. Equilibrium conditions and kinetics

81. Equilibrium conditions and kinetics of the intercalation of AiCl3 and FeCl3 with graphite

✍ Alfred R. Feichtinger; Alfons Baiker; Werner Richarz 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 255 KB

The amount of expansion on exfoliation is determined principally by the parent stage rather than the actual intercalate concentration. The amount of expansion increases with increasing stage of the parent compound before desorption. For the same parent stage, a higher concentration produces a larger

80. On the chemical reduction of FeCl3 g

80. On the chemical reduction of FeCl3 graphite

✍ R. Schlögl; H.P. Boehm 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 130 KB

The amount of expansion on exfoliation is determined principally by the parent stage rather than the actual intercalate concentration. The amount of expansion increases with increasing stage of the parent compound before desorption. For the same parent stage, a higher concentration produces a larger

Electrochemical preparation of the graph

Electrochemical preparation of the graphite bi-intercalation compound with H2SO4 and FeCl3

✍ H Shioyama; K Tatsumi; R Fujii; Y Mizutani 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 443 KB

Stage-n Fe&GICs (n = 2,3) prepared in the standard two-zone method were oxidized galvanostatically in H,SO,. The electrode potential vs. electric quantity curves observed during the treatment and the X-ray powder patterns of the products showed clearly the intercalation of H,SO, into FeCI,-GICs and

The intercalation of chromium trioxide i

The intercalation of chromium trioxide into graphite from a 6 M H2SO4 solution

✍ L.B. Ebert; J.C. Scanlon; L.A. Gebhard 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 311 KB

11. Mechanisms operative in growth of gr

11. Mechanisms operative in growth of graphite crystals from solution

✍ C Roscoe; D Nagle; S.B Austerman 📂 Article 📅 1969 🏛 Elsevier Science 🌐 English ⚖ 110 KB

York). A simple model of the deposition of pyrolytic carbon is proposed to explain the apparent inconsistencies between properties and structure. This model considers the importance of the nucleation rate, diffusion, and surface reactions and is based on structure determinations by density and stres

Intercalation process in the ternary sys

Intercalation process in the ternary system of FeCl3-NiCl2-KCl

✍ M Ohira; M Inagaki; Z.D Wang 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 609 KB

The intercalation process of FeCl, and NiClz into the natural graphite flakes with the average layer diameter of 400 pm was discussed on the basis of the chemical compositions of the compounds obtained in either the ternary system of FeCI,-NiCl,-KC1 or the binary system of FeCl,-NiCI, at 400°C. The

79. On the mechanism of intercalation of FeCl3 in graphite from solution

✦ Synopsis